Discounting sapience the only advantage humans have over other earth species is endurance. We evolved this way because instead of sprinting after our prey in the african savanna humans evolved to keep walking after it while tracking. We developed our brains for tracking, and then tool-making because of this.
The Na'vi on the other hand seem to have evolved around ambushing their prey with arrows. The result of this is that Na'vi should be far more effective sprinters, have better eyesight and awareness of their surroundsings and have more comprehensive non-verbal communication than humans.
Humans on the otherhand should have much better stamina and creativity.
Just some interesting extrapolation.

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